trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
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چکیده
منابع مشابه
Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) chloride toluene monosolvate
In the title compound, [PtCl(C(27)H(35)N(3))]Cl·C(7)H(8), the Pt(II) atom is coordinated in a pseudo-square-planar fashion by the N atoms of a 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine (tbtrpy) ligand and a Cl atom. The Pt-N distance of the N atom on the central pyridine is 1.941 (4) Å, while the peripheral N atoms have Pt-N distances of 2.015 (4) and 2.013 (4) Å. The Pt-Cl bond distance ...
متن کاملtrans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
The title compound, [RuCl(C(6)H(7)N)(2)(C(27)H(35)N(3))]PF(6)·C(3)H(6)O, was obtained unintentionally as the product of the reaction of 1,1'-methyl-enebis(4-methyl-pyridinium) hexa-fluoriso-phos-phate and RuCl(3)(tpy*) (tpy* is 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine) in the presence of triethyl-amine and LiCl. The mol-ecular structure of the complex displays an octa-hedral geometry aro...
متن کاملChlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate
In the title compound, [PtCl(C(27)H(35)N(3))]BF(4), the Pt(II) atom is in a pseudo-square-planar coordination, which is typical of Pt-terpyridine complexes. The Pt-Cl bond distance is 2.2998 (7) Å. The Pt-N distance of the N atom on the central pyridine is 1.931 (2) Å, while the peripheral N atoms have Pt-N distances of 2.018 (2) and 2.022 (2) Å. The cations pack as dimers in a head-to-tail ori...
متن کاملCrystal structure of trans-N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)oxamide methanol monosolvate
The here crystallized oxamide was previously characterized as an unsolvated species [Jímenez-Pérez et al. (2000 ▸). J. Organomet. Chem. 614-615, 283-293], and is now reported with methanol as a solvent of crystallization, C30H44N2O4·CH3OH, in a different space group. The introduction of the solvent influences neither the mol-ecular symmetry of the oxamide, which remains centrosymmetric, nor the...
متن کاملtrans-Carbonylchloridobis[dicyclohexyl(4-isopropylphenyl)phosphane]rhodium(I) acetone monosolvate
The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh-P = 2.3237 (6) and 2.3253 (6) Å, Rh-Cl = 2.3724 (6) Å, Rh-C = 1.802 (2) Å, P-Rh-P = 173.42 (2)° and Cl-Rh-C = 1...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812005594